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Yuexin Hou, Xiaoyun Li, Minghui Sun, Chaofan Li, Syed ul Hasnain Bakhtiar, Kunhao Lei, Shen Yu, Zhao Wang, Zhiyi Hu, Lihua Chen, Bao-Lian Su
《化学科学与工程前沿(英文)》 2021年 第15卷 第2期 页码 269-278 doi: 10.1007/s11705-020-1948-3
关键词: hierarchical zeolites single crystalline interconnected pores improved diffusion performance benzyl alcohol self-etherification reaction
《化学科学与工程前沿(英文)》 2023年 第17卷 第3期 页码 314-325 doi: 10.1007/s11705-022-2219-2
关键词: acceptorless alcohol dehydrogenation η5-C5Me5-Co metal–ligand cooperation theoretical calculation
石墨相氮化碳负载杂多酸——水相中高效光氧化苯甲醇 Article
吴立夫, 安赛, 宋宇飞
《工程(英文)》 2021年 第7卷 第1期 页码 94-102 doi: 10.1016/j.eng.2020.07.025
苯甲醛是一类重要化学品,在医药、化学合成和食品等领域具有广泛应用。然而,苯甲醛的生产过程通常涉及三氟甲苯或乙腈等危险溶剂的使用,并且,苯甲醛在水相反应体系中的转化率,尤其是选择性一直是难点。因此,开发一种环境友好的苯甲醛合成工艺具有极其重要的意义。在本文中,我们通过在磷酸功能化的石墨相氮化碳(g-C3N4)纳米片上负载磷钨酸成功制备了新型光催化剂(PW12-P-UCNS,其中,PW12为H3PW12O40·xH2O,P-UCNS为磷酸修饰的超薄石墨相氮化碳)。选取水相中苯甲醇光氧化制备苯甲醛的反应为模型反应,在室温条件下,对PW12-P-UCNS的催化性能进行了系统探究。所制备的PW12-P-UCNS光催化剂在2 h内的转化率为58.3%,选择性为99.5%,可重复使用5次以上,且活性未发生明显损失。同时,本文揭示了PW12-P-UCNS催化模型反应的Z型机理,系统分析了催化剂的光电流和光化学阻抗性能,并通过电子自旋共振测试和自由基捕获实验证明了超氧自由基和光生空穴是其主要反应活性物质。基于此,所设计的PW12-P-UCNS光催化剂对于在温和条件下通过水相光氧化反应生产苯甲醛具有广阔的应用前景。
《化学科学与工程前沿(英文)》 2023年 第17卷 第4期 页码 437-448 doi: 10.1007/s11705-022-2228-1
关键词: molybdenum oxides oxygen vacancies heterostructure electrocatalysts hydrogen evolution reaction
Study on direct alcohol/ether fuel synthesis process in bubble column slurry reactor
Zhen CHEN, Haitao ZHANG, Weiyong YING, Dingye FANG
《化学科学与工程前沿(英文)》 2010年 第4卷 第4期 页码 461-471 doi: 10.1007/s11705-010-0517-6
关键词: syngas alcohol/ether fuel slurry catalyst bubble column slurry reactor global kinetics mathematical model
Yan Zhang, Jian Xiao, Qiying Lv, Shuai Wang
《化学科学与工程前沿(英文)》 2018年 第12卷 第3期 页码 494-508 doi: 10.1007/s11705-018-1732-9
Electrolytic water splitting has been considered as a promising technology to produce highly pure H2 by using electrical power produced from wind, solar energy or other fitful renewable energy resources. Combining novel self-supporting structure and high-performance transition metal phosphides (TMP) shows substantial promise for practical application in water splitting. In this review, we try to provide a comprehensive analysis of the design and fabrication of various self-supported TMP electrodes for hydrogen evolution reaction, which are divided into three categories: catalysts growing on carbon-based substrates, catalysts growing on metal-based substrates and freestanding catalyst films. The material structures together with catalytic performances of self-supported electrodes are presented and discussed. We also show the specific strategies to further improve the catalytic performance by elemental doping or incorporation of nanocarbons. The simple and one-step methods to fabricate self-supported TMP electrodes are also highlighted. Finally, the challenges and perspectives for self-supported TMP electrodes in water splitting application are briefly discussed.
关键词: transition metal phosphide self-supported electrode electrocatalysis hydrogen evolution reaction
《化学科学与工程前沿(英文)》 2023年 第17卷 第10期 页码 1484-1502 doi: 10.1007/s11705-023-2331-y
关键词: polysulfone blend modification ultrafiltration membrane formation hydrodynamics poly(ethylene-co-vinyl alcohol) copolymer
Hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol on NiB/SiO2 amorphous alloy catalyst
SONG Yun, LI Wei, ZHANG Minghui, TAO Keyi
《化学科学与工程前沿(英文)》 2007年 第1卷 第2期 页码 151-154 doi: 10.1007/s11705-007-0028-2
关键词: following Brunauer electroless temperature transmission
Rui ZHU MD , Lin SHEN MD , Jianguo LIU MD , Weili ZHANG MM , Ling YANG MD ,
《医学前沿(英文)》 2009年 第3卷 第3期 页码 363-367 doi: 10.1007/s11684-009-0064-z
关键词: liver disease alcohol Zhihuang decoction CD14 signal transduction
Molecular diffusion in ternary poly(vinyl alcohol) solutions
《化学科学与工程前沿(英文)》 2022年 第16卷 第6期 页码 1003-1016 doi: 10.1007/s11705-021-2121-3
关键词: fluorescence correlation spectroscopy poly(vinyl alcohol) anomalous diffusion crowding effects dynamic light scattering binding effects rhodamine B
Using crosslinked polyvinyl alcohol polymer membrane as a separator in the microbial fuel cell
Yanping HOU, Kaiming LI, Haiping LUO, Guangli LIU, Renduo ZHANG, Bangyu QIN, Shanshan CHEN
《环境科学与工程前沿(英文)》 2014年 第8卷 第1期 页码 137-143 doi: 10.1007/s11783-013-0534-z
关键词: microbial fuel cell crosslinked polyvinyl alcohol (PVA) membrane separator material power generation coulombic efficiency
Degradation of bisphenol A by microorganisms immobilized on polyvinyl alcohol microspheres
Xue BAI, Hanchang SHI, Zhengfang YE, Qiujin SUN, Qing WANG, Zhongyou WANG
《环境科学与工程前沿(英文)》 2013年 第7卷 第6期 页码 844-850 doi: 10.1007/s11783-013-0487-2
关键词: bisphenol A polyvinyl alcohol immobilized microorganisms 4-hydroxybenzaldehyde
Recovery of free volume in PIM-1 membranes through alcohol vapor treatment
Faiz Almansour, Monica Alberto, Rupesh S. Bhavsar, Xiaolei Fan, Peter M. Budd, Patricia Gorgojo
《化学科学与工程前沿(英文)》 2021年 第15卷 第4期 页码 872-881 doi: 10.1007/s11705-020-2001-2
关键词: polymer of intrinsic microporosity (PIM) PIM-1 physical aging gas separation vapor-phase regeneration
Characterization of Bacillus amyloliquefacien contaminating 75% alcohol disinfectant
ZHANG Wanming, YUAN Yuesha, BIAN Cangli, TU Xianyu, ZHANG Wen, HUANG Huqiang, WANG Lan
《医学前沿(英文)》 2008年 第2卷 第1期 页码 113-116 doi: 10.1007/s11684-008-0021-2
GAO Sujun, SUN Yaqin, XIU Zhilong
《化学科学与工程前沿(英文)》 2007年 第1卷 第2期 页码 202-207 doi: 10.1007/s11705-007-0037-1
标题 作者 时间 类型 操作
The effect of hierarchical single-crystal ZSM-5 zeolites with different Si/Al ratios on its pore structure and catalytic performance
Yuexin Hou, Xiaoyun Li, Minghui Sun, Chaofan Li, Syed ul Hasnain Bakhtiar, Kunhao Lei, Shen Yu, Zhao Wang, Zhiyi Hu, Lihua Chen, Bao-Lian Su
期刊论文
Effects of ancillary ligands in acceptorless benzyl alcohol dehydrogenation mediated by phosphine-free
期刊论文
Oxygen-deficient MoO/NiS heterostructure grown on nickel foam as efficient and durable self-supportedelectrocatalysts for hydrogen evolution reaction
期刊论文
Study on direct alcohol/ether fuel synthesis process in bubble column slurry reactor
Zhen CHEN, Haitao ZHANG, Weiyong YING, Dingye FANG
期刊论文
Self-supported transition metal phosphide based electrodes as high-efficient water splitting cathodes
Yan Zhang, Jian Xiao, Qiying Lv, Shuai Wang
期刊论文
Uncovering the effect of poly(ethylene-co-vinyl alcohol) molecular weight and vinyl alcohol content on
期刊论文
Hydrogenation of furfuryl alcohol to tetrahydrofurfuryl alcohol on NiB/SiO2 amorphous alloy catalyst
SONG Yun, LI Wei, ZHANG Minghui, TAO Keyi
期刊论文
Effect of decoction on CD14 expression in lipopolysaccharide signal transduction pathway of alcohol-induced
Rui ZHU MD , Lin SHEN MD , Jianguo LIU MD , Weili ZHANG MM , Ling YANG MD ,
期刊论文
Using crosslinked polyvinyl alcohol polymer membrane as a separator in the microbial fuel cell
Yanping HOU, Kaiming LI, Haiping LUO, Guangli LIU, Renduo ZHANG, Bangyu QIN, Shanshan CHEN
期刊论文
Degradation of bisphenol A by microorganisms immobilized on polyvinyl alcohol microspheres
Xue BAI, Hanchang SHI, Zhengfang YE, Qiujin SUN, Qing WANG, Zhongyou WANG
期刊论文
Recovery of free volume in PIM-1 membranes through alcohol vapor treatment
Faiz Almansour, Monica Alberto, Rupesh S. Bhavsar, Xiaolei Fan, Peter M. Budd, Patricia Gorgojo
期刊论文
Characterization of Bacillus amyloliquefacien contaminating 75% alcohol disinfectant
ZHANG Wanming, YUAN Yuesha, BIAN Cangli, TU Xianyu, ZHANG Wen, HUANG Huqiang, WANG Lan
期刊论文